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The investigation of the impact of aerosol on air quality in Hong Kong using the GOCART model

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Title: The investigation of the impact of aerosol on air quality in Hong Kong using the GOCART model Authors: Zhang, Zhenxi (張禎璽) Abstract: In the study presented in this thesis we quantify the contribution of aerosols emitted from different source types and different regions to Hong Kong's air quality using the chemical transport model GOCART (Georgia Tech/Goddard Global Ozone Chemistry Aerosol Radiation and Transport). A new algorithm has been developed to isolate the emissions from different regions. This algorithm can account for the non-linear relationship between emission fluxes and the resulting concentrations in the GOCART model. Regarding the contributions of the major aerosol components, sulphur has the largest influence (68%) on the air quality in Hong Kong, followed by organic carbon (13%). The influence of dust (11%) and black carbon (5%) is relatively lower and sea salt is the lowest (3%). The highest AOD could be seen in September, mainly composed of sulphur aerosol (85%). The high AOD in March and April is caused by sulphur and organic carbon. Organic carbon has a relative contribution of 39% in March and 30% in April. For sulphur, black carbon and organic carbon, their anthropogenic emission in every continent, China and South China are considered. The aerosol produced by anthropogenic emission in Asia has the greatest contribution to Hong Kong, far greater than the total sum of other continents. The sulphur aerosol AOD in Hong Kong caused by anthropogenic SO2 emission is larger in spring and autumn than in other seasons. In spring and autumn, the sulphur aerosol from the northern part of China has bigger contribution to Hong Kong than other regions. The carbon aerosol (black carbon and organic carbon) AOD in Hong Kong produced by anthropogenic emission has larger value in spring, autumn and winter than that in summer. In autumn and winter, the carbon aerosol emitted from the China except South China has bigger contribution to Hong Kong than that emitted from other regions. For dust aerosol, the impact of dust coming from different deserts on air pollution in Hong Kong is investigated and compared. Regarding the vertical distribution of dust concentration in Hong Kong, the lower part of the atmosphere, from the ground to 2 km height, is mainly affected by Gobi dust aerosol with a concentration of about 10 μg/m3. However, in the middle to upper part of the atmosphere (above 5 km), Taklamakan dust aerosol is dominating. An analysis of the temporal variation reveals that the influence of Gobi and Sahara dust aerosol on Hong Kong mainly occurred in spring and winter, and Taklamakan dust in summer. Notes: CityU Call Number: QC882.42 .Z45 2012; xiii, 132 leaves : ill. (some col.) 30 cm.; Thesis (Ph.D.)--City University of Hong Kong, 2012.; Includes bibliographical references (leaves 123-132)

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